sources of silica in boiler water

Other impurities such as silica and iron can be tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. 2.1 Water-Tube Boilers ( Drum Type) - The feed water, boiler water and condensate, for water-tube boilers shall cotiply with the requirements given in Table 1. Its levels range from 1 part per million to more than 100 parts per million. Consequently, steam contamination has been steadily reduced. After the steam is used it is then dumped to the main condenser. In order to avoid these problems, the quality guidelines shown in Table IV have been adopted. For example, many higher-pressure boilers will require a higher quality of water with less contaminants than some lower-pressure boilers. Depending on the water source, time of the year, rainfall quantity, etc, there can be more colloidal silica in the water. The to overheating. The process of water treatment in boilers is not limited to producing high quality DM water. Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove. Although boiler feed water is treated to remove silica and other ionic contaminants, effective long-term control of silica can only be maintained by using the correct monitoring system. solids in boiler water Blowdown - Removes boiler water with a high concentration of solids which is replaced by feedwater containing a low concentration of solids WATER ... Silica 6 0 % Condensate 50 Basic Boiler Calculations. Silica is reaching out of control in super heated steam having value 3.2 to 4.0 PPM, but boiler feed water parameter is TDS-2, pH-8.6, P.Alkalinity-01, M.Alkalinity-02, Total hardness-00 and SILICA IS 00 PPM. The silica concentration is distributed between the water and vapour phases in a boiler. This can be written as: Example 3.12.3. Researchers have found that for any given set of boiler conditions using demineralized or evaporated quality makeup water, silica is distributed between the boiler water and the steam in a definite ratio. Calculate the feedwater composition (impurities) from make up and condensate analysis below Total Hardness M Alkalinity TDS 12. All impurities in the spray water enter directly into the steam. The subunits of colloidal silica particles are typically in the range of 1 to 5 nm. The only effective method for preventing excessive silica or other vaporous carryover is reduction of the boiler water concentrations. -s\$e!QbnÉùCb,�f¦ PhQ+C½S­rê}ÏØøblP›µ²‡Pä ü�!Rœ9ÕçÉDÓçÑP0†Bck`r ¯Ük¥3d79²Ll™®„QZB‹. ... tend to precipitate as mineral solids on the surfaces of pipes and especially on the hot heat exchanger surfaces of boilers. Other impurities such as silica and iron can be tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. There are two sources of CO2 in boiler water, viz. Calculate the feedwater composition (impurities) from make up and condensate analysis below Total Hardness M Alkalinity TDS Silica Scaling in Boilers. When boiler water pH is not within the proper range, calcium reacts with phosphate to form harmful calcium phosphate scale. Slowdown: Control of the concentration of chemicals in the boiler water by bleeding off a portion of the water from the boiler. All of About Steam Boiler, Heat Exchanger, Energy and Power Generation. Silica causes etching, scratching, and … 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. 3. Anthropogenic source of silica is relatively very small. The main natural source of silica is mineral quartz. Colloidal silica can cause serious problems of organic fouling of RO membranes because the An increase in temperature results in an increase in electrical conductivity. Initial acidification of a water-glass (sodium silicate) solution yields Si(OH) 4. There are no primary or secondary regulations for general silicates in drinking water, although there is a maximum contaminant level of seven million fibers longer than 10 microns for asbestos. The level of scaling on a boiler will be determined by the amount of these impurities in relation to the pressure a boiler is run at. The common impurities in raw water can be classified as follows: NOTE -In case of recovery boilers operating at low boiler pressures of I.5 to 2.0 The Journal of Geology 1957 , … There are no other sources of water as the ST condenser is an air cooled type, with no inleakage. Silica scaling can compromise the efficiency, performance, and safety of water using equipment such as boilers, turbines, piping, and even filtration systems. In the analyses of various surface and ground waters, silica content range from 1 to 107 ppm. When boiler water pH is not within the proper range, calcium reacts with phosphate to form harmful calcium phosphate scale. In rain hail and snow, silica content range from 1 to 2.8 ppm. Test kits are available to help detect dissolved silica levels in water. Are you at a risk of osteoporosis or have low bone mineral density? In the steam drum the feed water is then turned into steam from the heat. Suspended and dissolved solids in the boiler water tend to deposit in the steam and condensate system. Another common source of excessive impurities in steam is inadequate attemperation spray water purity. Silica in Boiler Water. Silica Dissolved from practically all rocks and soils, silica (SiO 2 ) is generally found in small amounts from 1 ppm to 30 ppm. Silica is frequently confused with hardness. For boiler water, the conductivity increases at the rate of approximately 2% (of the value at 25°C) for every 1°C increase in temperature. Boiler feed water quality is limited owing to problems of (1) scaling, (2) corrosion, and (3) foaming. The feed water is put into the steam drum from a feed pump. If silica is not present, the magnesium will precipitate as magnesium hydroxide. Calcium, magnesium, sodium, potassium, bicarbonate, sulfate, chloride, nitrate, and silica typically make up most of the dissolved solids in water. colloidal silica with 0.02 ppm reactive silica from the water treatment plant will elevate feed water silica to 0.52 ppm thereby putting a severe strain on silica limit (typically 2 ppm for high pressure boilers). the cause. High pH in the boiler water will reduce silica carryover from the boiler water. Load up on silica, along with calcium and vitamin D. Sir...I am facing a big problem with new High Pressure Boiler cleaning. R˜ú»ı³FğŠ\�B/-\¥#²R\ÿ-S=ºwRØñ¡Ë=1�ìQwã0Ìò¡Ü$Ìó±“ø.¸¥ÍÏL t_ÏŠ- ®«º|(ğdâ)¡”°è8nÄGÿ_ !>k?®¾ÏFò¾SĞ3ö÷‰év«Âƒ!R“7itE[Á´o£!In’¹j»&禈ƒ8šµ XŞ2£fÚ¶şÚö÷€ij$e©çòä¨HùÂ_�ÌË™õâ (¡à:ğæC°eÔ†ÀÒ Ğc ”6†�ÆCak6¡¤:ğåÃÀ€1ğè7ƒAÜÙPäßé®,@ˆg‹ú‚ÔÕPÂS ya² Ü!Ì#)pô9C•®l�q°À6E`éÃt*�øÛ’…ÖJˆæ`ë¨"xw‡À€Õ#hjA` $Ä7G�@AA䥆PÙ It can be admitted to the system when severe carryover occurs in evaporators processing water with a high Silica content. To get an idea of the enormity of the problem, let's consider a typical 500MW boiler boiling off 1,500 tonnes of water per hour. Disadvantages of Scale formation (1) Wastage of fuel : Scales have a poor thermal conductivity so the rate of heat transfer from boiler to inside water is greatly reduced. 3. This can be written as: Example 3.12.3. Deposit Analysis. Sometimes when a water softener is installed, it may seem that there still is hardness in the water because of etching or spotting. As the temperature and pressure are increased, more silica becomes present in the steam. As the boiler pressures increase above 400 psi, there is an increase in the tendency for silica to be selectively carried into the steam in amounts proportionate to the amount of silica present in the boiler water. The chloride concentration is controlled by boiler blowdown. Boiler water quality is of prime concern to all boiler operators. The presence of silica in water does not make problem for human kind because it is not toxic to living things. Any deposits found in the steam or condensate. The deposits may cause The conditions under which vaporous silica carryover occurs have been thoroughly investigated and documented. dissolved CO2 in raw water and CO2 formed by decomposition of bicarbonates in H2O according to the equation : Carbon dioxide presence of water forms carbonic acid which has a corrosive effect on the boiler material like any other acid. Volatilization and carryover of silica with the steam may cause hard, glassy siliceous deposits to form on turbine blades that reduce turbine efficiency. carryover. 4$Ô2‡€Ç$`¼Ñ†¡¦*KØ\ƒ|6°n.‡8Oƒpg“Ó¶b�SfæJ¼!Ñ,Ù ÃxuğâÁèN@a��¾>�Ï8&¼'ŒRĞ9P óƒ,Ö¯è¥ÊxE1&4È2Æa^J@Q ¡]’9†ğÙbÄ&!´0ÈÀÇà©K…’�4˨ɤ,¤ŠCӉ߉¬k5s ØB‰ª©œgƒñf h]SÜi—¦ Cont…. Slowdown: Control of the concentration of chemicals in the boiler water by bleeding off a portion of the water from the boiler. Other sources of such feedwater may be high Silica river or raw fresh water as well as distilled/deionized or unprocessed fresh water which has been stored and taken from cement-washed or silicatecoated tanks. Effects of Silica in Water. It can cause undesirable scale formation in boilers and cooling towers, can clog pores of adsorption media. Water quality can vary tremendously from one region to another depending on the sources of water, local minerals (see Figure 3.9.2). Silica. Chlorides may be maintained in the 60-200 range. Anthropogenic source of silica is relatively very small. Problems caused by carryover. Q. If insufficient boiler water alkalinity is being maintained, magnesium can combine with phosphate. Use interactive mappers to explore river dissolved solids loads and yields and determine the importance of different sources of contaminants in … Researchers have found that for any given set of boiler conditions using demineralized or evaporated quality make-up water, silica is distribute between the boiler water and the steam in a … External contamination could arise from: raw water ingress (demine plant) or drain line mix-up (wearing of seal or incorrect installation); use of silicon based lubricants and oils (result from leaky seals in the water system or turbine oil leaks or by silicon-based coatings on tubes used in replacement activity); feed water system (eg, un-reacted silicon) or chemical dosing of reagent problems (eg, caustic addition … Left improperly treated Such water is troublesome for boiler feed because of the formation of scale. Typically, silica exists in two forms in the water supply: (1) reactive silica; and (2) colloidal silica. Regulation. 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